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Real-time atomistic observation of structural phase transformations in individual hafnia nanorods.

Author
Abstract
:

High-temperature phases of hafnium dioxide have exceptionally high dielectric constants and large bandgaps, but quenching them to room temperature remains a challenge. Scaling the bulk form to nanocrystals, while successful in stabilizing the tetragonal phase of isomorphous ZrO, has produced nanorods with a twinned version of the room temperature monoclinic phase in HfO. Here we use in situ heating in a scanning transmission electron microscope to observe the transformation of an HfO nanorod from monoclinic to tetragonal, with a transformation temperature suppressed by over 1000°C from bulk. When the nanorod is annealed, we observe with atomic-scale resolution the transformation from twinned-monoclinic to tetragonal, starting at a twin boundary and propagating via coherent transformation dislocation; the nanorod is reduced to hafnium on cooling. Unlike the bulk displacive transition, nanoscale size-confinement enables us to manipulate the transformation mechanism, and we observe discrete nucleation events and sigmoidal nucleation and growth kinetics.

Year of Publication
:
2017
Journal
:
Nature communications
Volume
:
8
Number of Pages
:
15316
Date Published
:
2017
URL
:
https://doi.org/10.1038/ncomms15316
DOI
:
10.1038/ncomms15316
Short Title
:
Nat Commun
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