Real-time atomistic observation of structural phase transformations in individual hafnia nanorods.
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Abstract | :
High-temperature phases of hafnium dioxide have exceptionally high dielectric constants and large bandgaps, but quenching them to room temperature remains a challenge. Scaling the bulk form to nanocrystals, while successful in stabilizing the tetragonal phase of isomorphous ZrO, has produced nanorods with a twinned version of the room temperature monoclinic phase in HfO. Here we use in situ heating in a scanning transmission electron microscope to observe the transformation of an HfO nanorod from monoclinic to tetragonal, with a transformation temperature suppressed by over 1000°C from bulk. When the nanorod is annealed, we observe with atomic-scale resolution the transformation from twinned-monoclinic to tetragonal, starting at a twin boundary and propagating via coherent transformation dislocation; the nanorod is reduced to hafnium on cooling. Unlike the bulk displacive transition, nanoscale size-confinement enables us to manipulate the transformation mechanism, and we observe discrete nucleation events and sigmoidal nucleation and growth kinetics. |
Year of Publication | :
2017
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Journal | :
Nature communications
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Volume | :
8
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Number of Pages | :
15316
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Date Published | :
2017
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URL | :
https://doi.org/10.1038/ncomms15316
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DOI | :
10.1038/ncomms15316
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Short Title | :
Nat Commun
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