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Benzodichalcogenophenes with perfluoroarene termini.

Author
Abstract
:

Benzodichalcogenophenes are functionalized at their termini via SN Ar reactions of their bismetalates with perfluoroarenes. The identities of X, Y, and W are varied to study the effects on LUMO energy levels and crystallization motif. X-ray crystallography reveals that nearly all new derivatives crystallize with coplanar ring systems within slipped 1D or 2D pi-stacks.

Year of Publication
:
2008
Journal
:
Organic letters
Volume
:
10
Issue
:
20
Number of Pages
:
4421-4
Date Published
:
2008
ISSN Number
:
1523-7060
URL
:
https://doi.org/10.1021/ol801569m
DOI
:
10.1021/ol801569m
Short Title
:
Org Lett
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